G_? ( ( ( ( ( ( (K?? [1] To find the vapor pressure at a given temperature, use the Clausius-Clapeyron equation: ln (P1/P2) = (Hvap/R) ( (1/T2) - (1/T1)). The greatest source of decreasing solution-strength is through volatilization, as with fuming HCl or conditions that favorable stimulate vapor production (i.e. 0000232163 00000 n such sites. Use the boiling point calculator to find the boiling point at a given pressure for different substances such as water, hydrogen, methane, or others. All rights reserved. x=r8?j ltlO[13ARbuUV9I$D"/_mjr~yUmyy)/u_U{lK/owUq~Q?"!xd-"2HG;?._2x[$ y$1|6'T}^_da3Fpq,p (dqS1 %~>v\,S!_l DY@ BF,I/X801_ @'@m 4_ooBWi':/l5onm~wj`~ 0000010958 00000 n Obtain the water enthalpy of vaporization: 40660 J/mol. 0000011887 00000 n Consequently, if we reduce environmental pressure as it happens in reality at higher altitudes, we get a lower boiling point. Hydrochloric acid is a strong, monoprotic acid with a low pH capable of corrosive activities. the Acidic vapors generated from HCl solutions - i.e. On this online vapor pressure calculator page, you will learn what vapour pressure is, the significance of vapor pressure, and various fascinating facts about vapor pressure. The main flowrate shall be the vapor/air mixture during pumping in operation as the liquid level rises, it displaces the air/HCL/water vapor mixture above the liquid level into scrubber. The vapor pressure of a substance explains its behaviour with the temperature change. Partial Pressure Calculator ln102325PaP2=40660Jmol8.3145JmolK(1263K1280K)\small ln\frac{102325Pa}{P_2} = \frac{40660\frac{J}{mol}}{8.3145 \frac{J}{mol \cdot K}\cdot (\frac{1}{263K}-\frac{1}{280K})}lnP2102325Pa=8.3145molKJ(263K1280K1)40660molJ. Vapor Pressure Estimates Using Antoine Equation For example, water boils at 100 C when pressure is 1atm. Some of the commonly used liquids and their vapor pressures at 20 degrees centigrade are tabulated below: Methyl alcohol - 6.10.13 atm endstream endobj 28 0 obj <>stream Thus, when sufficient heat energy is given to a substance, it is a common phenomenon that it changes its state into the next freest state possible. According to guidance from theU.S. Environmental Protection Agency, fume scrubbers are an approved method of HCl vapor mitigation and often accompany bulk hydrochloric acid tanks. HCl-generated vapors will develop at ambient temperatures and the rate of produced gases will increase as temperatures and HCl concentrations rise, therefore, a proper venting system must remain intact and functioning properly or a venting schedule performed regularly. The form of the Antoine equation used here is: log10(P) = A - [B / (T + C)], where Pis the calculated vapor pressure in bar (on an absolute scale) and Tis the temperature in Kelvin. intended to imply recommendation or endorsement by the National or other vapor control device, an additional pressure/vacuum relief device with appropriate settings should be installed on the storage tank. With this vapor pressure calculator, we present to you two vapor pressure equations! See chart below outlining some common materials resistance to HCl: Hydrochloric acid-generatedvapors are corrosive and hazardous to health and workplace equipment. w !1AQaq"2B #3Rbr 0000006277 00000 n Mixtures of different molecules are never ideal, but we can treat them as if they were to simplify our calculations. FRP tanks have been used with great success in storing hydrochloric acid. Local regulatory statutes and codes may place additional requirements upon HCl secondary containment systems. Vapour Phase Mole Fraction using Henry Law in VLE Calculator Appendix a Useful Tables and Charts 0000349292 00000 n Hydrochloric acid is versatile and employed across various operations. Contact should be avoided, and the listed metals should not be used for HCl storage or other such applications. % Tank vents come in varied size and material, but are a component of successful and safe HCl storage. Vapor Pressure Calculator Formula:ClH Molecular weight:36.461 IUPAC Standard InChI:InChI=1S/ClH/h1HCopy IUPAC Standard InChIKey:VEXZGXHMUGYJMC-UHFFFAOYSA-NCopy CAS Registry Number:7647-01- Chemical structure: This structure is also available as a 2d Mol fileor as a computed3d SD file The 3d structure may be viewed using Javaor Javascript. Vapor pressure: 25.6287 bar: Viscosity: 1.3405E-4 Po: Gas density (at boiling point) 2.4329 kg/m 3: Gas density: . Equilibrium is a thermodynamic state of a substance where all of its possible forms (solid, liquid, gas/vapor) exist at the same time. HCl functions as a catalyst in the generation of MDI and TDI (isocyanates) in polyurethane manufacture. 18 0 obj <> endobj Engineering standards must contain 110% of total HCl tank system volume in the event of a release. Itkin, M.K. increased temperatures, decreased pressures). We can solve vapor pressure problems in either of two ways: by using Equation 13.6.1 to calculate the actual vapor pressure above a solution of a nonvolatile solute, or by using Equation 13.6.4 to calculate the decrease in vapor pressure caused by a specified amount of a nonvolatile solute. Fumes from HCl solutions are HCl gas and are considered noxious and potentially corrosive. The tanks begin to lose their chemical resistance when HCl concentrations approach and exceed 20%. Organic and Inorganic Compounds, Severe exposures can be fatal. Calculate the mole fraction of water (the solvent). partial pressure = total pressure mole fraction where mole fraction is the ratio of moles of the selected gas to the moles of the entire gas mixture. Hydrogen Chloride 0 A single liquid has more vapor pressure than a solution with two or more liquids. This situation is exacerbated when a solution is heated to near boiling. HTML 5 canvas support. If you have - keep reading. Formula: ClH Molecular weight: 36.461 IUPAC Standard InChI: InChI=1S/ClH/h1H IUPAC Standard InChIKey: VEXZGXHMUGYJMC-UHFFFAOYSA-N CAS Registry Number: 7647-01- Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file The 3d structure may be viewed using Java or Javascript . Corrosion-resistant containment basins, sumps, and double-walled tanks areacceptable forms of hydrochloric acid secondary containment. Contact the regional Air Liquide team for expertise service. Of note are the density, freezing/ boiling points, and solution strength concentrations. 2023 Protank. Tanks should be made to 1.9 specific gravity. 0000001516 00000 n Other Applications: Hydrochloric acid is also used in the production of fertilizers, dyes, and cleaning products. If P is the vapor pressure of the solvent, x is its mole-fraction and Pv is the vapor pressure of the pure solvent, then: The vapor pressure of a liquid mixture containing two liquids A and B is given by: where: Eng. It occurs at equilibrium, i.e., when the molecules are both vaporizing and condensing at the same rate at a particular pressure. Commonly known also as muriatic acid, hydrochloric acid is a strong, mineral acid known for its corrosive properties and general effectiveness across applications. The odor and pain thresholds for HCl mists are very low, meaning a persons nose can detect even minute concentrations of HCl in the air. been selected on the basis of sound scientific judgment. <> It describes the relationship between the vapor pressure and the temperature of a liquid. 0000290974 00000 n The chemicals industry uses hydrogen chloride to produce a large variety of organic chlorinated compounds. By Using Raoult's law: ; In the section below, State 1 (The normal boiling point), the calculator will show the . %PDF-1.4 % This millionaire calculator will help you determine how long it will take for you to reach a 7-figure saving or any financial goal you have. Vapor pressure gives information regarding volatility of a component i.e., high vapor pressure means. The presented data table and point graph exhibit some of hydrochloric acids properties. Yes. Resolve the vapor pressure equation considering the 2nd point pressure is 0.6 atm. 0000290421 00000 n The following components were used in generating the plot: Additonal code used was developed at NIST: As the solution warms, as from outdoor storage, HCl dissolved in solution will more easily volatilize and form toxic, gaseous hydrogen chloride above the solution surface. 0000007232 00000 n HCl is an important industrial and commercial acid that is employed in food-industry productions, oil recovery, metal refining, ore processing, chemical production, and cleaning products. HCl storage tanks should have vent scrubbers, as applicable; to ensure any emissions conform with governmental standards since HCl gas is a regulated air pollutant. Calculating equilibrium constant Kp using partial pressures Google Classroom Definition of equilibrium constant Kp for gas phase reactions, and how to calculate Kp from Kc. 0000289731 00000 n On newer browsers the following keyboard commands are supported: Click in or tab to the plot area to enable keyboard commands. 2023 by the U.S. Secretary of Commerce Partial pressure of different solutions of hydrochloric acid (w/w) as a HCl released to the atmosphere will react with water vapor to produce an HCl acid mist. [all data], Go To: Top, Antoine Equation Parameters, References. 0000007712 00000 n Polyethylene tanksmost notably XLPEare among the top tank-materials recommended for bulk hydrochloric acid storage and offer cost-effective service longevity. PDF Physical and Chemical Data 78 0 obj <>stream The selected tank resin is important. A common product of the steel pickling process is iron(III) chloride (ferrous chloride, FeCl3) which was long used in other applications, particularly wastewater flocculation, but the concentrations of other heavy metals from the pickling process has diminished the practice. Now you know how to calculate vapor pressure on your own. The following data tables are a compilation ofphysical and chemical propertiesfor muriatic acid. The Clausius-Clapeyron equation is a derivation of this formula. For further considerations, seeCAMEO Chemicals, a division of the National Oceanic and Atmospheric Administration (NOAA). Information It's also expressed by the following equation: Psolution=PsolventXsolvent\small P_{solution} = P_{solvent} \cdot X_{solvent}Psolution=PsolventXsolvent. All Rights Reserved. Some of our partners may process your data as a part of their legitimate business interest without asking for consent. PVC fittings, Hastelloy-C bolts, and Vitongaskets are the top recommended component-materials for HCl bulk storage. Muriatic acid is also utilized in the manufacture of aspartame, gelatin, fructose, citric acid, and hydrolyzed vegetable protein. dPdT=HTV\small \frac{dP}{dT} = \frac{H}{T \cdot \Delta V}dTdP=TVH. Now that you are equipped with the vapor pressure concepts, make your vapor pressure calculations simpler with our online vapor pressure calculator. Use the interactive controls above to simplify calculations and improve the efficiency of your distillation or evaporation requirements. Let's start with calculating the right side of our equation, as there are no unknowns: ln102325P2=1.1289\small ln\frac{102325}{P_2} = 1.1289lnP2102325=1.1289. * Gas density in atoms or molecules per volume, assuming a monatomic gas unless the substance is given as molecule. Even when dilute, it can be corrosive and dangerous. fuming hydrochloric acid - can quickly irritate mucosal membranes and lead to coughing and difficulty in breathing. The container, gaskets, bolts, fittings, and further equipment as applicable must be resistant in order to maintain their engineered integrity when housing bulk quantities of HCl. XA1$ #wCf12iu{ {[,kXXvpa @/Xd> }{' |XvH90HK2= v J7G Molarity values are approximations but demonstrate the low pH values of hydrochloric acid solutions. . 0000348698 00000 n Similarly, if the atmospheric pressure is further lowered to 0.25 bar, the boiling point of water reaches 65C. You can request a quote for ahydrochloric acid tankdirectly or contact us to discuss your project. The hazards of a strong acid should never be underestimated. Latent heat of vaporization (at boiling point). Toggle semilog (log Y) display if possible. 0000000016 00000 n Institute of Standards and Technology, nor is it intended to imply 0000368256 00000 n Desai, J. Phys Chem Ref Data . How do I need to calculate the flowrate of acid fume/vapour at the 8 vent inlet to design the scrubber? This is noteworthy when it comes to considering chemical storage, weight capacities, and engineering details of holding tanks. The vapor pressure is the pressure exerted by the surface molecules of a solid/liquid in the atmosphere. Moving the mouse pointer over or near a point will display the coordinates 0000003239 00000 n Abstract. Light molecules, those with high kinetic energy or those with weak intermolecular forces, have higher vapor pressures, and therefore a higher volatility - the tendency to vaporize. It plays a significant role in classifying a substance as hazardous. Water has an enthalpy of vaporization of 40660. (866) 345-0695, Your browser is not supported. Standard Reference Data Act. Hydrochloric Acid Aerosols | US EPA Low Flow in Pipes- posted in Ankur's blog. HCl regenerates ion-exchange resins by replacing built-up cations with hydrogen ions, which rejuvenates the exchange resin, re-enabling it for further use. H\n0y Stull, Daniel R., Hydrogen chloride is used in semiconductor fabrication for etching of native oxide, Chemical Vapor Deposition (CVD) reactor cleaning or moisture getter. ~:_W}u7cyLYr#NgDc r$b3*]`z-$x. 0000002495 00000 n Concrete containment dikes with acid-resistant coatings are another common choice. 0000008986 00000 n Toluene - 9.20.03 atm The fuming nature of HCl, especially of increased concentrations, is another important factor in bulk HCl storage as the gaseous fumes can be corrosive to the immediate tank environment. The following equation demonstrates the reaction: The above reaction establishes an equilibrium but chemical properties and reactivity significantly favor production of the hydronium and chloride ions. Enthalpy of vaporization or, in other words, the heat of vaporization, is the energy required for a phase change - turning a liquid into a gas. We and our partners use cookies to Store and/or access information on a device. Ensure airtight manways and connections. click the mouse on the plot to revert to the orginal display. Set up an equation using Dalton's law, rearrange the equation to solve for the pressure of just the hydrogen gas, plug in your numbers, and solve: So, the partial pressure of hydrogen gas trapped in the tube is 98.1 kPa. The following pie graph as well as application-excerpts fromPubCHEMprovide some insight into HCl categories and example applications. One of the most stable industrial acids, HCl still presents significant corrosion hazards and storage difficulties. Dont forget to explore our other online calculators and the fascinating aspects we uncovered for you on those pages. Calculate Vapor Pressure and Boiling Point using Aspen HYSYS - YouTube 0000005343 00000 n Also known as the salt-sulfuric acid method, the Manheim Process reacts a salttypically sodium chloride or potassium chloridewith sulfuric acid at temperatures up to 1,100oF, where the reaction drives the formation of hydrochloric acid and a sulfate-salt. %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz If there are more than two components in the solution, Dalton's law of partial pressures must be applied. Hvap is the Enthalpy (heat) of Vaporization and R is the gas constant (8.3145 J mol-1 K-1). A typical phase diagram for a single-component material, exhibiting solid, liquid and gaseous phases. The 33% HCL solution is in equilibrium with the vapor mixture. According to Raoults Law, the vapor pressure of a solution is directly proportional to the mole fraction of the solute. by Alek Eccles It is 86.35C. 0000003629 00000 n NIST subscription sites provide data under the As stated previously, HCl is generated as a by-product of another chemical process. 0000003125 00000 n Hydrochloric acid will corrosively attack un-lined concrete. 0000290019 00000 n Successful hydrochloric acid storage incorporates materials and components resistant to the strong acids corrosive effects as well as methods to mitigate any potential HCl vapors. Concentrated grades are considered 35-38 wt% HCl and are considered fuming hydrochloric acid due to the release of HCl gas from the solution. Horrigan, Canadian Metallurgical Quarterly, 23, 309 (1984). Notice: A plot could not be displayed here becuse plotting 0000157373 00000 n Last modified: 2019-09-25 22:10 by Michael Schmid. Vapor pressure is directly related to the kinetic energy of a molecule. Manage Settings An example of data being processed may be a unique identifier stored in a cookie. shall not be liable for any damage that may result from 0000349197 00000 n Non-mitigated HCl vapors are fully capable of causing health effects and corroding sensitive materials. The majority of HCl ismanufacturedon-point (on-site), and a portion of HCl produced this way comes as the by-product of another process, a concept termed captive-use. In a general calculation for strong acids, the pH of the solution is equal to the negative log of the solutions molarity:pH = -log[molarity], and as such, HCl solutions of 1M (M, for molarity) or greater will have negative pH values, indicative of the health and safety hazards the chemical presents. Key points The equilibrium constant, K_\text p K p , describes the ratio of product and reactant concentrations at equilibrium in terms of partial pressures. 3 0 obj Lower strength solutions are produced through dilution. If you would like to change your settings or withdraw consent at any time, the link to do so is in our privacy policy accessible from our home page.. Vapor Pressure of Anhydrous Hydrogen Fluoride-10 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 Temperature, oF Gage Pressure, Pounds per Square Inch. from publication: HazMat Liquid Release Following a Tank Truck . HClis an aqueous solution made from this hydrogen chloride gas dissolved in water. Shipping information Packaging information US xA and xB are the mole fractions of liquids A and B respectively. 0000348328 00000 n the value. Tank capacities range from 35 to 20,000 gallons. Polypropylene tanks are best reserved for smaller quantities (5 45 gallons) and more dilute hydrochloric acid solutions. 0000003012 00000 n if(typeof ez_ad_units!='undefined'){ez_ad_units.push([[300,250],'engineeringunits_com-large-mobile-banner-1','ezslot_6',126,'0','0'])};__ez_fad_position('div-gpt-ad-engineeringunits_com-large-mobile-banner-1-0');The Antoine equation is: We and our partners share information on your use of this website to help improve your experience. The boiling point of AHCl at one atmosphere pressure (14.7 psia, 760 mmHg) is -85C (-121F) and the vapor pressure of AHCl at ambient temperature of (20C, 68F) is 603 psia. Molar concentrations greater than one will bring solution pH beneath zero. Many common storage materials that are resistant to HCls corrosive effects retain their resistance as concentration increases. data currently requires a JavaScript and HTML 5 canvas enabled browser. Brandani, S., Brandani, V. and Di Giacomo, G., 1994. Our Raoult's law calculator is a convenient tool to calculate the vapor pressure of an ideal solution. TheKavalue for HCl is reportedat 1.3 x 106where sulfuric acid is 1.0 x 103. 0000349123 00000 n 3 Ways to Calculate Vapor Pressure - wikiHow Hydrogen chloride endobj It's much easier to use a scientific calculator or, as long as you are here, our vapor pressure calculator :). I believe that once the acid vapour flowrate is known, I can calculate the pressure drop in the vent line to design the scrubber fan. 0000349010 00000 n Everything else will be guess. Concentrated hydrochloric acid has a lower boiling point and increased vapor pressure. You can rearrange the above equation to solve for P2\footnotesize P_2P2: P2=102325e1.1289=33090Pa\small P_2 = \frac{102325}{e^{1.1289}} = 33090\space PaP2=e1.1289102325=33090Pa. As you see, it's a bit complicated to do this calculation by hand. When a liquid contains two or more immiscible liquids, irrespective of their concentration, the temperature of distillation depends on their vapor pressure. When transporting or transferring large quantities of hydrochloric acid to a storage tank, a fume scrubber or other means of fume/pressure dissipation is needed to mitigate the increased pressure arising from displacing saturated vapor spaces. PDF Hydrogen chloride. (HCl) An equation of state for hydrochloric acid solutions. 0000349063 00000 n Hence, vapor pressure increases with an increase in the surface area of the liquid. What happens to the vapor pressure of a liquid when we add a non-volatile solute to it? Let you measure the velocity of the gas entering the scrubber and then multipying by the section you will get the flow rate . Snyder Industries,Inc., in their position statement, recommend tanks of 1.9 specific gravity rating, PVC fittings, Vitongaskets, and Hastelloy bolts. The chemical is not considered sensitive to the effects of ultraviolet energy, although the suns heat-contribution is a storage concern due to the increased potential for HCl gas formation. You can calculate vapour pressure using the following formulae: Vapor pressure is calculated by using the Clausius-Clapeyron equation as shown here: P1 and P2 are the vapor pressures at two temperatures T1 and T2. The following graph shows how steadily the vapor pressure of various liquids increases with temperature. Keep calculating with us, for free every single time! Common HCl concentration freezing points indicate freezing is not a general concern. While solving problems in physics and chemistry, it's important to remember to convert your units. At boiling point at 1.013 bar. Effective hydrochloric acid FRP tanks are fabricated and lined with a corrosion resistant barrier. from the hydrochloric acid are contained by the system. Hence, the plot would be shaped in a straight line. For the best experience, you should, Nationwide Authority in Liquid Handling. trailer Your institution may already be a subscriber. The chemical density of hydrochloric acid is around that of water, making it generally lighter than other common industrial chemicals. When these data were not available or unreliable (e.g. The pH of an HCl solution will be low, even for dilute mixtures, with a pH around zero or below to be expected for pure, concentrated solutions. To make this calculation, the water vapor fraction when the gas is saturated with water vapor is needed. When atmospheric pressure is reduced, the vapor pressure of water increases and water turns into vapor at a much lesser temperature. Even though the density is low, storage tank specific gravity ratings of at least 1.9 are still recommended due to the hazards and vapor pressures of muriatic acid. Temperature and Vapor or Saturation Pressure for some common Fluids At atmospheric pressure saturation temperature of water : 100 oC (212 oF) ethyl alcohol : 78.5 oC (173 oF) Liquids - Vapor Pressure Approximate vapor pressure for temperatures in the range 20 oC - 25 oC (68 oF - 77 oF). Even when dilute, it can be corrosive and dangerous. What is the shape of the plot of the vapor pressure of a solvent in a solution? 0000006961 00000 n Isotopologues: T = temperature (K). Continue with Recommended Cookies. Saturated Vapor Pressure Calculator online: Definition of Antoine Equation Definition provided by wikipedia: The Antoine equation is a class of semi-empirical correlations relating the vapor pressure and temperature for pure components. PDF Hydrochloric Acid Hcl PDF Hydrofluoric Acid Properties - Purdue University Storage tank components should be chosen based upon their HCl durability. This is why vapor pressure increases with an increase in temperature. National Institute of Standards and Other inorganic compounds produced using hydrochloric acid includes water treatment and paper production chemicals, such as iron(III) chloride and polyaluminium chloride (PAC), which serve as flocculation and coagulation agents in the treating of water, both sewage and potable and in paper production. Putting it simply, the molecules of a substance always exert force on the atmosphere. The vapor pressure of liquid mixtures is calculated by using Raoults Law. Liquid Phase. The corrosive activity between the acid and metal will generate hydrogen gas, a potentially flammable, explosive, and corrosive gas. Further calculations of water volume in the gas involved calculation of the dry fraction or percentage of water in the gas stream. The change in vapor pressure of a pure substance as temperature changes can be described using the equation known as the Clausius-Clapeyron Equation: (1) l n P 2 P 1 = H v a p R ( 1 T 1 1 T 2) Where: P1 is the partial pressure of the liquid at T1 P2 is the partial pressure of the liquid at T2 Example 1 Boiling Point Calculator I think what you are missing is the basis of your calculation: Dalton's Law, which states P (Total) = P (A) + P (B) where, P (Total) = System pressure; your initial 760 mmHg P (A) = partial pressure of your solvent, 83 mmHg P (B) = partial pressure of another gas in the vapor space; possibly Nitrogen (or air?) Ind. Polypropylene or PVC are additionally effective material choices for FRP linings in hydrochloric acid storage. D3 B!w m lc!7C,_ 1|}6>,74$$dA o K ?i_y[bN#[+O:^1\J+n]kqy.suP8:e8[aKTFXiJUk:u9VQ. Hydrochloric acid is an inorganic strong acid utilized across various applications. <>/ExtGState<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> 0000014955 00000 n Secondary containment measures are required for bulk quantities of hydrochloric acid due to its chemical hazards. No raw data such as these can cover all conditions of concentration, temperature, humidity, impurities and aeration. ?7?6MM58VK==K Hydrochloric acids characteristic to generate corrosive HCl gas is a main concern. When there is a big difference between the specific volume of a molecule's gas phase and its condensed phase, we can derive the following equation: lnP1P2=HR(1T21T1)\small ln\frac{P_1}{P_2} = \frac{\Delta H}{R \cdot (\frac{1}{T_2}-\frac{1}{T_1})}lnP2P1=R(T21T11)H. Hydrochloric acid vapors are corrosive and hazardous, as well as a regulated emission. Recommendations : Air Liquide has gathered data on the compatibility of gases with materials to assist you in evaluating which materials to use for a gas system. When and how do I use the Clausius-Clapeyron equation? Olive Branch, MS 38654 %%EOF Note: Vapour pressure decreases with an increase in the intermolecular forces of the liquid. 0000016501 00000 n Violent reactions are known to occur between hydrochloric acid and acetic anhydride, ammonium hydroxide, calcium phosphide, sodium hydroxide, 2-aminoethanol, ethylenediamine, perchloric acid, chlorosulfonic acid, propylene oxide, silver perchlorate/carbon tetrachloride, calcium carbide, rubidium carbide, vinyl acetate, magnesium boride, and mercury(II) sulfate. The unit of pressure doesn't matter as long as it's the same for both initial and final pressure. Go To: Top, Antoine Equation Parameters, Notes, Stull, 1947 What is the relation between the surface area of the liquid and its vapor pressure?
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